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chap_19_review - NH 2 R C Cl O R C N H O R reduction 1...

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1. 2. R C Cl O 3. 4. 5. Chap 19 Review 6. 7. 8. R NH 2 3CH 3 I R N(CH 3 ) 3 I - + heat R + N(CH 3 ) 3 + H 2 O + 2R' NH 2 R C N H O R' R C H H C N(CH 3 ) 2 H R' MCPBA or H 2 O 2 R' H H R Heat + N(CH 3 ) 2 HO R NH 2 NaNO 2 , HCl R N N + Cl - Ar N N + CuX X = Cl,Br,-CN Ar X + N 2 H 3 PO 2 Ar H + N 2 Cl - Ar N N + + H-Ar' (activated) Ar N N Ar' R C O R' R C N R' OH H 2 N OH H + reduction R C H R' NH 2 1 0 R'' NH 2 R C N R' R'' reduction R C H R' R'' N H 2 0 R N H R R C N R' R R + NaBH 3 CN R C H R' R N
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Unformatted text preview: NH 2 R' C Cl O + R' C N H O R reduction 1) LiAlH 4 2) H 2 O R' H 2 C N H R 9. R NO 2 H2/ catalyst (Ni,Pd, Pt) or active metal Fe, ZN, Sn R NH 2 NaHCO 3...
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