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Ch.+17+class+notes

Ch.+17+class+notes - -0.0 • uow-0=\x N-0 • a-0 •...

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Unformatted text preview: ------0 .0 • uow+-' --0=\x N-0 • a-0 « • +-' C/) -Q) ..c c.. a=\ 0 C/) . -Q) Q) t) > ::::J +-' cuC >0> -c C Q) e -0 I +-'-0C/) __ '+-t) o CO C 0 + .. +-oJ CO S ..c ('-0 0 V C) <J co-s.... 0 +-oJ 0 CO '+-c 0 +-oJ CO .-E E ~ s.... +-oJ en '+-0 E en.-0 \ .. :l, cJ I Addition of strong nucleophiles to acid derivatives o II R' -II o-".-J; ..~R 01 : For which of the following does X not create an acid derivative? A. OH D. E. Addition of weak nucleophiles o OHk .... , + XH~x.. ~ R'YH, H+ ~ J ~...,--YR~ A 0 yR• ~ x = NH, NR, OR , CI 03. What controls the oA. .klnetics-._-..~~-BC thermodynamicsC. sterics ~---~....=-, _"' D. solvent • E. a-b~f0rrn ation ~~ -----0 t) co o '+-' Q) -0 en --Q) o>< __ > L-'-+-' -0 co ~> ..c -c '+-(]) 0-0 C o -'+-' -0 -0 « ",. 0=\x Addition of weak nucleophiles R'o R'XH,W-AR ~R - -( Y:JR):RXR' x = NH, NR', 0 IJ\j) A. Imine, XR' = H2NR' ~-:lVjrB. Rydrazone, XR' = H2N~HR) I . \_C. Oxime, XR' =H2NOtL-\{' "'{Ine, X = NR' v I( (!J , (l--tJ -f2 ~~ Addition of weak...
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Ch.+17+class+notes - -0.0 • uow-0=\x N-0 • a-0 •...

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