11-20-08 - What cofactor? Desaturase In plants and yeast...

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What cofactor?
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Desaturase In plants and yeast there is hydroxylation instead of desaturation
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Glucocorticoids stimulate fatty acid release from adipose tissue
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Heme generated tyrosine radical abstracts this proton
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COO - COO - O H H O H COO - O O COO - O O COO - O O O O COO - O O O O
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O H Fe 3+ COO - O O O O COO - O O O OH H A COO - O O OH Fe 5+ - HO H + + 2 e - Fe 3+ OH 2
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O H Fe 4+ - HO O Fe 3+ OH 2 How is the radical generated in the first place?
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Fe 3+ - HO H H H Fe 2+ OH 2 H O O H O O Fe 2+ HO H H O OH Fe 3+ - HO
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OPP PPO OPP H B OPP
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OPP H B H- H+
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Flavin monooxygenase
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O H A HO H B H H HO Methyl and hydride transfera H HO
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This note was uploaded on 09/20/2011 for the course CHM 4034 taught by Professor Staff during the Summer '11 term at University of Florida.

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11-20-08 - What cofactor? Desaturase In plants and yeast...

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