Physical Chem Notes-Practice 14

Physical Chem Notes-Practice 14 - The numbers refer to the...

Info iconThis preview shows page 1. Sign up to view the full content.

View Full Document Right Arrow Icon
Exercises to prepare for Feedback #1 The numbers refer to the Exercises (not Problems) in Physical Chemistry , 8 th Edition , by Peter Atkins and Julio De Paula. Numerical answers for the (b) exercises these are available in the back of the textbook, and more complete answers are in the Student Solutions Manual. A) The standard Gibbs Free Energy change for isomerization of 5-hydroxy-2-pentanone to 4,5- dihydro-2-hydroxy-2methylfuran is -4.0 Kcal/mole at 25 ° C. Calculate K at 25 ° C. 7.1 7.3 7.5 7.7 Also, for 7.7a, Will the reaction shift to make more borneal or isoborneal, or is it already at equilibrium? 7.9 7.11 Answers A) 860 7.7 (a) +12.3 kJ/mole Needs to make more borneal to reach equilibrium ---------------------------------------------------------------------------------------------------------------------
Background image of page 1
This is the end of the preview. Sign up to access the rest of the document.

Unformatted text preview: The numbers refer to the Exercises (not Problems) in Physical Chemistry , 9 th Edition , by Peter Atkins and Julio De Paula. Numerical answers for the (a) exercises these are available in the back of the textbook, and more complete answers are in the Student Solutions Manual. 6.3 Also, at Q=0.010, determine whether the reaction needs to shift towards reactants or products in order to reach equilibrium. 6.6 6.9 6.13 6.15 6.17 Answers: 6.3 At Q = 0.01 G r is -44.3 KJ/mole, so the reaction must shift to the products to reach equilibrium) 6.13 Q = 2 which is more than K (K is less than 1.0) so shift to borneal (reactant) to reach equilibrium 14...
View Full Document

This note was uploaded on 09/20/2011 for the course CHM 4411 taught by Professor Ohrn during the Spring '08 term at University of Florida.

Ask a homework question - tutors are online