Organic 2 Review Problem 557

Organic 2 Review Problem 557 - 226 306 323 35 326 320 335...

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542 TABLE X. AROMATIC KETONES AND DERIVATIVES. Acetophenone . o-Chloro-acetophenone m- ,, P- » »> o-Bromo- ,, m- P- » " ; * W- ,, ,, o-Hydroxy- m- P- » ,, o-Methoxy- m- ,, ,, . . />- . . 0-Nitro- m " ,, ,, . . P- M . . Propiophenone . Benzyl methyl ketone . Benzyl ethyl Benzophenone . />-Chloro- „ />-Bromo- ,, T Phenyl />-to!yl ketone . Benzyl phenyl ,, . Di-/>-tolyl ,, . Di benzyl ketone. Methyl- 1 -naphthyJ ketone . Methyl-2- M ,, Benzoin Benzil ... . Phenacyl chloride Phenacyl bromide />-Bromophenacyl bromide . Benzalacetone . Dibenzalacetone i-Tctralone Fluorenone M.p. 20° 20 5i 28 96 109 38 28 81 8r 19 27 49 78 82 60 60 95 35 34 54 137 95 59 50 109 42 112 83 B.p. 202° 229 228 232 112/ IO I3I/I6 2 5 6 215 296 240 245 240 258 218 202
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Unformatted text preview: 226 306 323 35 326 320 335 S3' 302 344 347^-244 I35/I8 262 120/12 ^/ 341 Phenyl-hvdraxone M.p. 105 114 126 no 151 114 142 128 132 147 87 137 106 126 109 116 100 128 146 177 io6 2 /'34f \235* J57 153 84 151 2,4-Dlnitro-hydrazone M.p. 2 5 0 206 231 189 230 261 159 207 220 228 191 156 239 185 230 199 204 229 I OO 262 245 189 ZIZ 230 227 i So 257 283 Smi-carbaxone M.p. I 9 8 1 60 232 2OO 177 238 208 210 195 IQ9 183 I 9 6 IQS 257 181 198 135 164 121 I 4 S 140 I 4 6 229 2 3 6 2o6d. 1827 244^.* 156 146 187 190 217 1 See Phenacyl bromide (below). 2 Second form, m.p. 159. * Di-deriv. f Mono-deriv....
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This note was uploaded on 09/19/2011 for the course CHM 2211 taught by Professor Castalleano during the Fall '06 term at University of Florida.

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