Organic 2 Review Problem 559

Organic 2 Review Problem 559 - (72) (161) (58) 250 (77) 290...

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544 TABLE XII. AROMATIC CARBOXYLIC Acid (i) Benzoic (a) Salicylic (3) Acetylsalicylic (4) m-Hydroxybenzoic (5) p- (6) o-Chlorobenzoic . (7) m- (8) P- (9) o-Bromobenzoic . (10) m- (") P- (12) o-Methoxybenzoic (13) m- (u) p- * . (15) o-Nitrobenzoic (16) m- (17) />- (18) 2,4-Dinitrobenzoic ('9) 3,5- (ao) Anthranilic . (21) m-Aminobenzoic . (22) P- (23) o-Toluic (24) w- „ (25) p- (26) Phthalic (27) Isophthalic , (28) Terephthalic (39) Phenylacetic (30) a-Phenylpropionic (31) P- » (3«) Cinnamic (33) o-Nitrocinnamic . (34) p- (35) J/-Mandelic (36) i-Naphthoic (37) 2-Naphthoic (38) Hexahydrobenzoic (39) Phenoxyacetic M.p. 121 158 135 201 213 HI 158 243 ISO 155 252 101 no 184 147 141 239 183 207 146 174 1 88 105 in 178 196-9*/. 347 300 subl. 76 (265) 48 133 240 287 118 162 185 30 100 Esters Methyl B.p. 198° 223 (49) (70) (131) ^34 234 (44) 244 (32) (81) 245 (32) 250 (48) 256 275 (78) 279 (96) (70) (108) (24) 300 (38) (112) 215 215 (33) 217 283 (68) (HO 215 221 238 (36) 26l
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Unformatted text preview: (72) (161) (58) 250 (77) 290 183 245 Ethyl B.p. 213 234 272 (72) 295 (116)297 243 245 238 254 261 262 261 250 263 (30) 275 (47) 298 (56) (41) (95) (13)226 294 (92) 227 (47) 230 228 298 (11)285 (42) 302 227 230 247 271 (44) (142) (37) 255 3<>9 (32) 308 196 251 Phcnyl M.p. 69 42 97 176 37 65 117 59 76 99 129 146 70 173 (306) 83 70 I2O 191 43 72 152 99 60 benzyl M.p. 8 9 98 90 108 181 106 107 130 no 105 141 "3 132 112 142 l6 9 142 IS7 205 201 >248 91 8? 104 155 203 264 65 36 117 13* 186 124 132 Pbenacyl M.p/ 119 no 105 147 178 83 116 90 83 113 90 134 5 1 06 128 i8i 4 i86 4 75 103 154 191 192 50 42 140 126 146 84 135 148 Values in parentheses in the columns for Methyl, Ethyl and Phenyl Esters and for Anhydrides and Nitriles are M.ps. 1 Anisic acid....
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This note was uploaded on 09/19/2011 for the course CHM 2211 taught by Professor Castalleano during the Fall '06 term at University of Florida.

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