Organic 2 Review Problem 563

Organic 2 Review Problem 563 - 6 217 IQI 211 206 214 I...

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548 TABLE XIV. SULPHONIC ACIDS AND DERIVATIVES. Benzene t»ulphonic Toluene-o-sulphonic . Toluene- w- ,, Toluene-/>- o-Chlorobenzene sulphonjc . w- ,, »> P" »* 0-Bromobenzene ,, m- ,, , P- o- Nitrobenzene w- ,, ., P- it »» Orthanilic 1 Mctanilic 1 Sulphanilic £-Acetamido-benzene sulphonic . Phenol-p-sulphonic . o-Carboxy-bcnzene sulphonic 3 w- M n * P- .1 n ' Naphthalene- 1 -sulphonic . NaphthaIene-2- i -Naphthylamine-4- , , 2-Naphthylaminc- 1 -sulphonic 2- „ -6- „ i -Naphthol-2-sulphonic i- M -4- n 2 -Naphthol- 1 -sulphonic 2- „ -6- „ Anthraquionne- 1 -sulphonic Anthraquinone-2- Benzene-o-disulphonic Benzenc-m- ,, Benzene-^- ,, Benzyl- tbJouronium salt M.p. 150° 170 182 175 170 I 4 6 132 I 4 S l8 7 248 l6 9 206» 133* 2I 3 * 137 191 195 139 l8 4 170 104 I 3
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Unformatted text preview: 6 217 IQI 211 206 214 I SuJphonyl chloride M.p. 15 10° 12 7« 28 Liq. 53 5i Liq. 75 69 64 80 ISO 40, 79** 20» 57* 68 79 124 217 197 H3 63 141 SuJpboD-amide M.p. 153° 156 108 137 188 148 144 1 86 154 1 66 J 93 168 179 153 142 164 219 177 t I 7 O* 236« 150 217 206 238 261 254 229 288 SuJphoa-anilide M.p. 110° I 3 6 96 103 104 119 "5 126 136 200 141 195* 252* "2, 157 132 i go 200 i6i 5 161 216 193 241 144 249 1 o-Aminobenzene sulphonic acid. * m-Aminobenzene sulphonic acid. 8 o-, w-, />-Sulphobenzoic acids. 4 Two forms. 8 Dihydrate, m.p. 105°. * Di-substituted deriv. t Imide (saccharin) has m.p 224°. (continued on p. 549)...
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This note was uploaded on 09/19/2011 for the course CHM 2211 taught by Professor Castalleano during the Fall '06 term at University of Florida.

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