Organic 2 Review Problem 566

Organic 2 Review Problem 566 - 240 300 228 172 102 230 352...

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TABLE XVI. PRIMARY AMINES AND DERIVATIVES— continued. o-Am inophenol m- ., . P- 2,4-Dichloro-aniline 2,4-Dibromo- ,, 2,4,6-Trichloro- ,, 2,4,6-Tribomo- ,, i-Naphthylamine 2- ,, . 0-Phenylene-diamine m- „ ,, P- p-Amino-dimethylaniline />-Amino-diethyl ,, 2-Amino-biphenyl M.p. i?4 123 1 86 63 79 78 1 20 50 H3 102 6 4 141 41 50 *- , » » • i 53 4,4'-Diamino- ,, (benzidine) 127 B.p. 245 262 300 300 294 257 283 267 262 261 299 302 400 Picrate M.p. 1 06 124 83 163 195 208 184 1 88 Acetyl deriv. M.p. 124* 101* 151* I 4 6 I 4 6 206 2 3 8 1 60 134 186 191 3°4 132 104 121 171 317* Denzoyl deriv. M.p. 184* 153* 234* 117 134 i?4 198 161 162 303*
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Unformatted text preview: 240* 300* 228 172 102 230 352* Benzene sulph-onyl deriv. M.p. 134* 153* 125* 128 Toluene £-sulph-onyl deriv. M.p. I39 1 I57 2 I43 3 126 134 232 167 1 02 185 194 247 157 Phenyt-urea deriv. M.p. 166 232 221 222 d. 133 I 220 2O2 172 266 i 2 3 2* 99 1 60 243* 1 N-deriv. 2 N-deriv. 3 N-deriv. O-deriv. has m.p. 101°. O-deriv. has m.p. 96°; di-deriv. m.p. 110°. O-deriv. has m.p. 143°; di-deriv., m.p. 169°. ' Indicates di-substituted derivative....
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This note was uploaded on 09/19/2011 for the course CHM 2211 taught by Professor Castalleano during the Fall '06 term at University of Florida.

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