Organic 2 Review Problem 567

Organic 2 Review Problem 567 - (255) (254) (258) 103 43 S 5...

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552 TABLE XVII. SECONDARY AMINES. Dimethylamine Diethylamine . Di-H-propylamine . Di-iso-propylamine Diallylamine , Di-«-butylamine Di-iso-butylamine . Di-wc.-butylamine . Di-n-amylamine Dibenzylamine Dicyclohexylamine . N-Methyl-aniline . N-Ethyl-aniline N-H-propyl-aniline . N-n-butyl- ,, N-Benzyl- N-Methyl-o-toluidine N-Methyl-m- „ . N-Methyl-/>- „ , N-Ethyl-o- „ . N-Ethyl-m- „ . N-Ethyl-/>- „ . Diphenylamine ,, . Di-o-tolylamine Di-w- Di-p- Pyrrolidine Piperidine Tetrahydro-quinoline Tetrahydro-iso- „ Piperazine 1 Morpholine . Carbazole M.p. 38 54 79 20 104 238 B.p. 7-5° 56 in S 4 in i$9 139 135 205 300*/. * 5 6 194 206 222 240 306 208 2O6 2IO 218 221 217 3 02 312* 322 330 S 9 105 250 232 HS 130 354 Plcratc M.p. 158° 155 75 140 59 119 173 HS 138 48 90 I3i 182 112 15^ I 4 2 195 280« I 4 S l8 5 Acetyl A A •>• • • aeriv. M.p. (166) (186) (210) 86 93 IO2 103 54 47 Uq. 58 56 66 83
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Unformatted text preview: (255) (254) (258) 103 43 S 5 Liq. (295) 46 144* 69 Ben-zoyt-!_'_. aertv. M.p. 41 42 112 77 63 60 56 107 66 53 72 72 40 1 80 125 48 76 129 196* 75 98 Benzene suiph-onyl j__j_. acnv. M.p. 47" 42 51 55 68 79 54 119 64 62 66 124 94 67 154 282 118 Toluene -sulph-onyl j _ _. acnv, M.p. 79 60 81 119 94 88 56 56 140 120 60 75 ?i 142 123 103 298* H7 Phen-yl-urea deriv. M.p. 85 S 5 105 127 169 IQ 4 QI '36 171 144 Nitrosamine M.p. Liq. Liq. 46 Liq. 61 105 Liq. 58 54 67 IOI Liq. 53 158* 29 84 B.p. 177 205 195 237 214 I2lf X34t 218 2i4<f 245 1 Hexahydrate, m.p. 44. * At 730 mm. * Di-substituted derivs. f At 14-15 mm. Values in parentheses are B.ps....
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This note was uploaded on 09/19/2011 for the course CHM 2211 taught by Professor Castalleano during the Fall '06 term at University of Florida.

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