Organic 2 Review Problem 568

Organic 2 Review Problem 568 - 3-. . . 2- Brotnopyridine 3...

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553 TABLE XVIII. TERTIARY AMINES AND DERIVATIVES. Trimethylamine Triethylamine Tri-»-propylamine . Tri-iso-propylamine . Tri-n-butylamine Triallylamine ... . Tribenzylaminc Tricyclohcrylamine . Dimethylanilinc Ethylmethylaniline . Diethylaniline ... . Di-ti-propylaniline Di-iso-propylaniline . Di-»-butylaniline Dibenzylaniline Benzylmethylaniline . Benzylethylaniline />-Chloro-dimethylaniline . p-Bromo- ,, p-Iodo- Dirnethyl-o-toluidine Dimethyl -m- . Dimethyl-p- „ . Dimethyl- 1 -naphthylamine Dimethyl-2- ,, Methyldiphenylamine Triphenylamine Tri-o-tolylamine Tri-m- .. . Tn-p .. . Pyridine ... . 2-Methylpyridine (z-picoline) 3- »> (3- » ) 4- »» (4- », ) 2,4-Dimethylpyridine (lutidine) . 2,6-
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Unformatted text preview: 3-. . . 2- Brotnopyridine 3 -. . . M.p. 92 70 35 55 47 127 117 B.p. 3'5 90 156 216 155 380 193 201 216 245 221 271 300 306 31* 230 264 185 212 211 273 305 295 365 US 129 144 143 157 142 172 170 149 194 170 Picrate M.p. 216 173 117 1 06 190 179 I6 3 134 142 26l 5 132 127 121 122 131 130 145 206 I6 7 170 ISO I6 7 I8 3 I6 3 I 5 6 135 Meth-iodide M.p. 2 3 0 208 1 80 184 228rf. 125 102 156 135 164 141 185* 212 2IO 177 220 l6 4 193*/. 163 118 229 99 152 "3 238 146 Metho-picrate M.p. 122 114 1 08 197 i95<*-1 68 "5 "3 I2O ISO Metho-toluene-f>-*ul-pnonate M.p. 161 49 1 80 85 83 139 150 120 127 I 5 6 NiIr(MO deriv. M.p. *7 66 84 91 44 62 (continued on p. 554)...
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