Organic 2 Review Problem 572

Organic 2 Review Problem 572 - chloride...

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557 TABLE XXI. NITRO-COMPOUNDS. Nitro-methane Nitro-ethane Nitrobenzene m-Dinitrobenzene o-Nitro-toluene . P- » > » 2,4-Dinitro- ,, sym-Trinitro- ,, . o-Nitro-phenol m- ,, ,, . 2,4-Dinitro- „ . Picric acid . o-Nitro-aniline m- ,, ,, P" »» o-Nitro-acetanilide JH- ,, ,, P" » »» o-Nitro-anisole P" » - » o- ,, -phenetole P- >» • » 2,4-Dinitro-anisole 2,4- „ -phenetole . o-Nitro-benzyl alcohol . "*" >i »» » P" »i »» M.p. Liq. » » 90 Liq. 52 70 82 46 97 114 114 122 71 114 I 4 S 92 155 212 IO 54 Liq. 60 94 86 74 27 93 B.p. 101° 114 210 302 220 23« 216 285 265 259 268 283 2jod. o-Nitro-benzyl chloride *w- » P- />-Nitro-benzyl bromide . />-Nitro ,, iodide o-Nitro-benzaldehyde w- M » />- >» f » o-Nitro-benzoic acid f - »> » >» P~ » » » o-Nitro-benzoyl chloride . "I- I) »i » />- » »» 3,5-Dinitro-benzoyl
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Unformatted text preview: chloride o-Chloro-nitrobenzene /> - > o-Bromo- />- i - i o-Iodo- ,, /> M ~ M Chloro- 2,4-dinitro-benzene . Bromo- 2,4-dinitro-benzene . i -Nitro-naphthalene *~ > M.p 48 45 ?i 99 127 44 58 1 06 148 141 241 25 35 75 70 33 83 43 126 54 172 Si 75 61 79 B.p. 27? 244 242 261 259 315 304 TABLE XXII. AZO-COMPOUNDS. Azo-bcnzene . . . . . />-Amino-azo-benzene p-Dimethylamino-azo-benzene . Benzene-azo-(/>)-phenol . Benzene-azo-z-naphthol . Azo-o-toluene . . . . Azo-^-toluene . . . . Formula 0,H 5-NiN-C 4 H 6 NH 1-C-H 4-NiN-C 1 H, (CH t ) t N.C.H 4-N:N-C.H C t H,-N:N'C,H 4 OH C.H -N:N-C 10 H f OH CH,C.H 4-N:N-C f H 4 CH, > M.p. 68 126 us 152 134 55 144...
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This note was uploaded on 09/19/2011 for the course CHM 2211 taught by Professor Castalleano during the Fall '06 term at University of Florida.

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