This preview shows page 1. Sign up to view the full content.
Unformatted text preview: gives only one product on monochlorination. A-9. Write the propagation steps for the light-initiated reaction of bromine with methylcyclo-hexane. A-10. Using the data in Table B-1 of this Study Guide, calculate the heat of reaction ( H ) for the light-initiated reaction of bromine (Br 2 ) with 2-methylpropane to give 2-bromo-2-methylpropane and hydrogen bromide. A-11. ( a ) Write out each of the elementary steps in the reaction of tert-butyl alcohol with hydrogen bromide. Use curved arrows to show electron movement in each step. ( b ) Draw the structure of the transition state representing the unimolecular dissociation of the alkyloxonium ion in the preceding reaction. CH 3 CH 2 O 2 NH 3 1 ( a ) CH 3 CH 2 CH 2 OH ? SOCl 2 ( b ) ? CH 3 CH 2 C(CH 3 ) 2 HBr Br OH Cl ( a ) ( b ) CH 3 Br ( a ) ( b ) CH 3 CH 2 CHCH 2 CHCH 3 CH 2 OH CH 2 CH 3 86 ALCOHOLS AND ALKYL HALIDES...
View Full Document
- Spring '01
- Organic chemistry