2423Chapt6

2423Chapt6 - CHAPTER 6 - Practice Exercises (ORGANIC CHEM I...

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CHAPTER 6 - Practice Exercises (ORGANIC CHEM I ) ________DR. PAHLAVAN 1. Calculate the degree of unsaturation in the following formulas; a) C 8 H 18 ( octane) b) C 8 H 10 N 4 O 2 (Caffeine) c) C 14 H 9 Cl 5 (DDT) d) C 20 H 32 ClN 2. Rank the following sets of substituents in order of priority according to the Cahn-Ingold-Prelog sequence rules. (highest = 1 , lowest =4) a) –OH -OCH 3 - COOH -CHO b) –CH=CH 2 -CH 2 OH -CH 2 OCH 3 -CH 2 CH 3 c) –Br -CH 3 -OH -H 3. Assign E or Z configuration of the following alkenes; a) C = C CH 3 CH 2 OH CH 3 CH 2 CH 3 b) C = C CH=CH 2 COOCH 3 CHO CH 3 CH 2 c) C = C H CH 3 d) C = C OH OCH 3 CH 3 e) C = C NC CH 2 NH 2 CH 2 NHCH 3 CH 3 -CO-HN 4. Draw structures corresponding to the following systematic names; a) 1-isopropyl-4-methylcyclohexene b) 3-butyl-2-heptene c) 4-methyl-1,2- hexadiene d) trans-3,3-dimethyl-4-propyl-1,5-octadiene e) (4Z) –2,4-diethyl-1,4-hexadiene f) 1,2-propadiene g) (3Z,5E) –2,6-dimethyl-1,3,5,7-octatetraene h) cis-2,2,5,5- tetramethyl-3-hexene
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2423Chapt6 - CHAPTER 6 - Practice Exercises (ORGANIC CHEM I...

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