2425Chapt16

2425Chapt16 - 0BUCHAPTER 16- (Benzene Derivatives -Practice...

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CHAPTER 16- (Benzene Derivatives -Practice Exercises) CHEM 2425 Dr. Pahlavan / Dr. Cherif / Dr. Dessens 1. Reactions -Give the major product for each of the following electrophilic aromatic substitution (EAS) reactions. CH 3 a. Cl 2 / FeCl 3 Br 2 / FeBr 3 b. SO 3 H NO 2 c. I 2 / CuCl 2 d. Cl SO 3 / H 2 SO 4 CH 3 HNO 3 / H 2 SO 4 excess e. CH(CH 3 ) 2 C O Cl f. AlCl 3 g. HNO 3 / H 2 SO 4 CN OCH 3 CH 3 Cl / AlCl 3 h. SO 3 / H 2 SO 4 CH 3 i. COOCH 3 Br 2 / FeBr 3 j. I NaNH 2 /NH 3 k. KMnO 4 /H 2 O heat l. CH 3 KMnO 4 / H 2 O heat m. CH 2 CH 2 CH 3 KMnO 4 / H 2 O heat n. KMnO 4 / H 2 O heat CH 3 CH 3 o. KMnO 4 / H 2 O heat p. CH 3 OCH 3 Br 2 / FeBr 3 q. HNO 3 / H 2 SO 4 CH 3 NO 2 r. CH 3 Cl Cl 2 / FeCl 3 s. NBS / CCl 4 radical initiator t. u. Li/ NH 3 Birch reduction 2. Synthesis -beginning with the compound shown on the left, suggest a synthesis for each of the compounds shown below. Clearly show all intermediates and reaction conditions. Several steps are required for each synthesis conversion. Cl
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2425Chapt16 - 0BUCHAPTER 16- (Benzene Derivatives -Practice...

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