2425Chapt21

2425Chapt21 - left. Clearly show all intermediates and...

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Carboxylic Acid Derivatives (21) 1. Nomenclatures For each of the compounds shown below, provide an acceptable IUPAC name. Cl O O O O NH 2 O OCH 3 O C N O Cl O N H CH 3 O C N a. b. c. d. f. g. O h. i. j. 2. Carboxylic Acid Derivatives—Synthesis a. For each of the reactions below, predict the major organic product. CH 3 CH 2 OH H + NH(CH 3 CH 2 ) 2 SOCl 2 OH NH 2 CH 3 CH 3 I OH PBr 3 H + /H 2 O CH 3 COOH SOCl 2 CH 2 N 2 O OH C Cl O COOH CH 3 O CH 3 O O O O CH 3 H COO CH 3 O O CO OH C N O N H H O C l CH 3 H CO OH a. b. c. d. e. f. CH 2 CH 3 g. h. i. j. k. l. 1
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b. suggest a synthesis for each of the compounds shown below, beginning with the starting material shown on the
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Unformatted text preview: left. Clearly show all intermediates and reaction conditions. Br O O O CH 3 a. b. O NH 2 OH c. d. CH 3 3. Carboxylic Acids DerivativesReactions LiAlH 4 HLiAl(O(CH 3 ) 3 ) 3 CH 3 MgBr (C 6 H 5 ) 2 CuLi C 6 H 5 MgBr DIBAH (CH 3 ) 2 CuLi LiAlH 4 LiAlH 4 LiAlH 4 LiAlH 4 CH 3 MgBr O OH C Cl O CN CH 3 O CH 3 O O H CN CH 3 O O CN CN O N H H O Cl CH 3 O Cl CN a. b. c. d. e. f. g. h. i. j. k. l. 2...
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This note was uploaded on 09/24/2011 for the course CHEM 1411-12 taught by Professor Pahlavan during the Spring '10 term at HCCS.

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2425Chapt21 - left. Clearly show all intermediates and...

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