2425Chapt24

2425Chapt24 - Chapter 24 Review-Amines and Arylamines 1....

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Chapter 24 Review-Amines and Arylamines 1. Amines and Arylamines-Nomenclature For each of the compounds shown below, provide an acceptable IUPAC name. NH 2 NH 2 NH 2 NH 2 NH 2 CH 3 CH 3 H NH 2 NH 2 CH 3 H H NH 2 N CH 3 CH 3 CH 2 CH 3 CH 2 N H a. b. c. d. e. f. g. h. i. 2. Amines and Arylamines-Synthesis a. For each of the reactions below, predict the major organic product. Cl O NH 2 SO 2 Cl CH 3 N O O K Br NH CH 2 Br NH 2 O C Cl O NH 2 1 . NaN 3 2 . heat,H 2 O 1 . 2 . OH - / H 2 O NaOH, Br 2 , H 2 O NH O CH 3 Br H H O OCH 3 O NH 2 O H NH CH 3 CH 3 NH 2 NH NaBH 3 CN, H 3 O + 1 . LiAlH 4 ,ether 2 . H + /H 2 O 1 . NaN 3 , ethanol 2 . LiAlH 4 ,ether /H + , H 2 O O 1 . CH 3 Br (excess) 2 . Ag 2 O, H 2 O, heat a. b. c. d. e. f. g. h. i. j. k. l. 1
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b. Suggest a synthesis for each of the compounds shown below, beginning with the starting material shown on the
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2425Chapt24 - Chapter 24 Review-Amines and Arylamines 1....

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