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Lecture 19- end Ch6

Lecture 19- end Ch6 - Lecture 20 Reactions of Alkenes...

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Unformatted text preview: Lecture 20 Reactions of Alkenes Hydroboration Oxidations Reductions End Ch. 6 : : : Announcements : : : HW 6 posted today CH 310/318M – Sp.2011 Last Time • Finish Electrophilic Additions – Alkene Hydrations V. Patman 2 CH 310/318M – Sp.2011 Tues 4.05.11 V. Patman 2 CH 310/318M – Sp.2011 Oxidations & Reductions • Oxidation: • Reduction: V. Patman 3 CH 310/318M – Sp.2011 Tues 4.05.11 V. Patman 3 CH 310/318M – Sp.2011 Ozonolysis • Alkene Cleavage by Ozone – BREAK C-C bonds!!!! • Structure of Ozone: resonance structures, very weak π-bond V. Patman 4 CH 310/318M – Sp.2011 H 3 C H 3 C CH 3 1.) O 3 2) (CH 3 ) 2 S H 3 C O CH 3 H 3 C O ketone aldehyde Tues 4.05.11 V. Patman 4 CH 310/318M – Sp.2011 Ozonolysis • Mechanism: V. Patman 5 CH 310/318M – Sp.2011 H 3 C H 3 C CH 3 1.) O 3 2) (CH 3 ) 2 S H 3 C O CH 3 H 3 C O ketone aldehyde O S CH 3 H 3 C DMSO ( a byproduct) Tues 4.05.11 V. Patman 5 CH 310/318M – Sp.2011 Dihydroxylation V. PatmanV....
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Lecture 19- end Ch6 - Lecture 20 Reactions of Alkenes...

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