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Lecture 18- Ch6-rxns

Lecture 18- Ch6-rxns - Lecture 18 Reactions of Alkenes...

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Unformatted text preview: Lecture 18 Reactions of Alkenes Hydroboration Oxidations Reductions : : : Announcements : : : CH 310/318M – Sp.2011 Last Time • Electrophilic Additions V. Patman 2 CH 310/318M – Sp.2011 Thurs 3.31.11 V. Patman 2 CH 310/318M – Sp.2011 Hydroboration • Reaction: • BH 3 (borane): Thurs 3.31.11 V. Patman 3 CH 310/318M – Sp.2011 Herbert C. Brown, Purdue Hydroboration • Mechanism: – Part 1: addition of borane Thurs 3.31.11 V. Patman 4 CH 310/318M – Sp.2011 Thurs 3.31.11 V. Patman 5 CH 310/318M – Sp.2011 Hydroboration • Mechanism: – Part 2: Oxidative cleavage of C-B bonds Thurs 3.31.11 V. Patman 6 CH 310/318M – Sp.2011 Hydroboration • Mechanism: – Part 3: Hydrolysis of boronic ester Alkene Hydration • Summary of methods Thurs 3.31.11 V. Patman 7 CH 310/318M – Sp.2011 Practice • Predict the products of the following. Show stereochemistry when relevant, and provide both products if a racemic mixture is produced.provide both products if a racemic mixture is produced....
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Lecture 18- Ch6-rxns - Lecture 18 Reactions of Alkenes...

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