CH318 - Final Review - Michael Tam Reactions Review 1....

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Michael Tam Reactions Review 1. [EA]Addition of HX Reagents: Alkene + HX Products: Haloalkane Regioselectivity: Markovnikov Stereo selectivity: None Note: 1,2 Shifts 2. [EA]Acid Catalyzed Addition of H 2 0 Reagents: Alkene + H2SO4 + H2O Products: Alcohol Regioselectivity: Markovnikov Stereo selectivity: None Note: 1,2 Shifts 3. [EA]Addition of X2 Reagents: Alkene + X2 + CH2Cl2 Products: Dihaloalkane [Racemic or Meso] Regioselectivity: Markovnikov Stereo selectivity: Anti Note: if original Alkene is Z, then the mixture is racemic if original Alkene is E, then mixture is meso This reaction starts with a Bridged Halomonium Ion 3 Resonance Structures 4. [EA]Addition of HOX Reagents: Alkene + H2O + X2 Products: Halo Hydrin AKA Halo Alcohol [racemic] Regioselectivity: Markovnikov
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Stereo selectivity: Anti Note: This Reaction starts with a bridged Halomonium Ion 2 Resonance structures 5. [Oxidation]Hydroboration Reagents: Alkene + BH3 + H2O2 + NaOH Products: Alcohol (alkane) [Racemic] Regioselectivity:
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This note was uploaded on 09/25/2011 for the course CH 318M taught by Professor Bocknack during the Spring '08 term at University of Texas at Austin.

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CH318 - Final Review - Michael Tam Reactions Review 1....

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