AlphaCarbon_notes

AlphaCarbon_notes - Ketones Competition of two...

Info iconThis preview shows pages 1–32. Sign up to view the full content.

View Full Document Right Arrow Icon
Acidity of α -Hydrogens the anion is stabilized by resonance Compare the following p K a ’s: H 2 C O CH 3 H 2 C CH 2 H H H 2 C H CH 3 20 42 50 The electrons are better accommodated on O than on C
Background image of page 1

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full DocumentRight Arrow Icon
The p K a values of some carbon acids
Background image of page 2
Esters and Amides Are Less Acidic Than Aldehydes and
Background image of page 3

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full DocumentRight Arrow Icon
Background image of page 4
Background image of page 5

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full DocumentRight Arrow Icon
Background image of page 6
Background image of page 7

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full DocumentRight Arrow Icon
Background image of page 8
Background image of page 9

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full DocumentRight Arrow Icon
Background image of page 10
Background image of page 11

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full DocumentRight Arrow Icon
Background image of page 12
Background image of page 13

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full DocumentRight Arrow Icon
Background image of page 14
Background image of page 15

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full DocumentRight Arrow Icon
Background image of page 16
Background image of page 17

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full DocumentRight Arrow Icon
Background image of page 18
Background image of page 19

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full DocumentRight Arrow Icon
Background image of page 20
Background image of page 21

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full DocumentRight Arrow Icon
Background image of page 22
Background image of page 23

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full DocumentRight Arrow Icon
Background image of page 24
Background image of page 25

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full DocumentRight Arrow Icon
Background image of page 26
Background image of page 27

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full DocumentRight Arrow Icon
Background image of page 28
Background image of page 29

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full DocumentRight Arrow Icon
Background image of page 30
This is the end of the preview. Sign up to access the rest of the document.

Unformatted text preview: Ketones Competition of two delocalization pathways The acidity of the -hydrogen at the sp 3 carbon flanked by two carbonyl groups is much higher: These compounds also have acidic -hydrogen:...
View Full Document

This note was uploaded on 09/25/2011 for the course CHEM 2262 taught by Professor Smith during the Spring '08 term at LSU.

Page1 / 32

AlphaCarbon_notes - Ketones Competition of two...

This preview shows document pages 1 - 32. Sign up to view the full document.

View Full Document Right Arrow Icon
Ask a homework question - tutors are online