Dolbier HW Solutions 211

Dolbier HW Solutions 211 - 205 NUCLEOPHILIC SUBSTITUTION (c)

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( c ) ( d ) ( e ) ( f ) (g) A-2. Choose the best pair of reactants to form the following product by an S N 2 reaction: (CH 3 ) 2 CHOCH 2 CH 2 CH 3 A-3. Outline the chemical steps necessary to convert: ( a ) ( b ) A-4. Hydrolysis of 3-chloro-2,2-dimethylbutane yields 2,3-dimethyl-2-butanol as the major product. Explain this observation, using structural formulas to outline the mechanism of the reaction. A-5. Identify the class of reaction (e.g., E2), and write the kinetic and chemical equations for: ( a ) The solvolysis of tert -butyl bromide in methanol ( b ) The reaction of chlorocyclohexane with sodium azide (NaN 3 ). A-6. ( a ) Provide a brief explanation why the halogen exchange reaction shown is an acceptable synthetic method: ( b ) Brie f y explain why the reaction of 1-bromobutane with sodium azide occurs faster in
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This note was uploaded on 09/26/2011 for the course CHM 2210 taught by Professor Reynolds during the Fall '01 term at University of Florida.

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