B-6.Which of the following phrases are notcorrectly associated with an SN1 reaction?1.Rearrangement is possible.2.Rate is affected by solvent polarity.3.The strength of the nucleophile is important in determining rate.4.The reactivity series is tertiary. secondary. primary.5.Proceeds with complete inversion of confguration.(a)3, 5(b)5 only(c)2, 3, 5(d)3 onlyB-7.Rank the following in order of decreasing rate of solvolysis with aqueous ethanol(fastestAslowest):(a)2.1.3(b)1.2.c.3.1(d.3.2B-8.Rank the following species in order of decreasing nucleophilicity in a polar protic solvent(mostAleast nucleophilic):(a)3.1.2(b.3.c.3.d.1.3B-9.From each of the following pairs select the compound that will react faster with sodiumiodide in acetone.2-Chloropropaneor2-bromopropane121-Bromobutaneor2-bromobutane34(a)1, 3(b)1, 4(c)2, 3(d)2, 4B-10.
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This note was uploaded on 09/26/2011 for the course CHM 2210 taught by Professor Reynolds during the Fall '01 term at University of Florida.