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Dolbier HW Solutions 282 - 276 ARENES AND AROMATICITY A-6...

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A-6. Give the reactant, reagent, or product omitted from each of the following: A-7. Provide two methods for the synthesis of 1-bromo-1-phenylpropane from an aromatic hydrocarbon. A-8. Write the structures of the resonance forms that contribute to the stabilization of the inter- mediate in the reaction of styrene (C 6 H 5 CH ? CH 2 ) with hydrogen bromide in the absence of peroxides. A-9. Write one or more resonance structures that represent the delocalization of the following carbocation. A-10. An unknown compound, C 12 H 18 reacts with sodium dichromate (Na 2 Cr 2 O 7 ) in warm aque- ous sulfuric acid to give p - tert -butylbenzoic acid. What is the structure of the unknown? PART B B-1. The number of possible dichloronitrobenzene isomers is ( a ) 3 ( c ) 6 ( b ) 4 ( d ) 8 B-2. Which of the following statements is correct concerning the class of reactions to be expected for benzene and cyclooctatetraene? ( a )
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