Dolbier HW Solutions 306

Dolbier HW Solutions 306 - 2 SO 4 , H 2 O, heat ( d ) 1....

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B-15. Which sequence of steps describes the best synthesis of 2-methyl-3-pentanone? ( a ) 1. 1-Propanol 1 (CH 3 ) 2 CHMgBr, diethyl ether 2. H 3 O 1 3. PDC, CH 2 Cl 2 ( b ) 1. 1-Propanol 1 Na 2 Cr 2 O 7 , H 2 SO 4 , H 2 O, heat 2. SOCl 2 3. (CH 3 ) 2 CHCl, AlCl 3 ( c ) 1. 1-Propanol 1 PCC, CH 2 Cl 2 2. (CH 3 ) 2 CHLi, diethyl ether 3. H 3 O 1 4. Na 2 Cr 2 O 7 , H
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Unformatted text preview: 2 SO 4 , H 2 O, heat ( d ) 1. 2-Propanol 1 Na 2 Cr 2 O 7 , H 2 SO 4 , H 2 O, heat 2. CH 3 CH 2 CH 2 Li, diethyl ether 3. H 3 O 1 4. PCC, CH 2 Cl 2 O 2-Methyl-3-pentanone 400 ALCOHOLS, DIOLS, AND THIOLS...
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This note was uploaded on 09/28/2011 for the course CHM 2210 taught by Professor Reynolds during the Fall '01 term at University of Florida.

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