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Dolbier HW Solutions 348 - 442 ALDEHYDES AND KETONES...

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( k ) An oxime is formed when cyclopentanone is treated with hydroxylamine. ( l ) Hydrazine reacts with cyclopentanone to form a hydrazone. ( m ) Heating a hydrazone in base with a high-boiling alcohol as solvent converts it to an alkane. ( n ) A p -nitrophenylhydrazone is formed. ( o ) Cyclopentanone is converted to a semicarbazone on reaction with semicarbazide. ( p ) A Wittig reaction takes place, forming ethylidenecyclopentane. Triphenylphosphine oxide (C 6 H 5 ) 3 P O Ethylidenetriphenyl- phosphorane (C 6 H 5 ) 3 P CHCH 3 Ethylidenecyclo- pentane CHCH 3
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