Dolbier HW Solutions 495

Dolbier HW Solutions 495 - butanedicarboxylate ClCH 2 CH 2...

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( c ) ( d ) ( e ) ( f ) ( g ) ( h ) ( i ) 5-Oxo-5-phenylpentanoic acid Diethyl 4-oxo-4-phenylbutane- 1,1-dicarboxylate C 6 H 5 CCH 2 CH 2 CH 2 COH O O C 6 H 5 CCH 2 CH 2 CH(COOCH 2 CH 3 ) 2 O 1. HO 2 , H 2 O 2. H 1 3. heat Diethyl malonate CH 2 (COOCH 2 CH 3 ) 2 Phenyl vinyl ketone Diethyl 4-oxo-4-phenylbutane- 1,1-dicarboxylate 1 NaOCH 2 CH 3 CH 3 CH 2 OH C 6 H 5 CCH CH 2 O C 6 H 5 CCH 2 CH 2 CH(COOCH 2 CH 3 ) 2 O Diethyl cyclobutane-1,1-dicarboxylate O O COCH 2 CH 3 COCH 2 CH 3 1. HO 2 , H 2 O 2. H 1 3. heat Cyclobutanecarboxylic acid O COH Diethyl 4-chloro-1,1-butanedicarboxylate ClCH 2 CH 2 CH 2 CH(COOCH 2 CH 3 ) 2 NaOCH 2 CH 3 Diethyl cyclobutane-1,1-dicarboxylate O O COCH 2 CH 3 COCH 2 CH 3 Diethyl malonate CH 2 (COOCH 2 CH 3 ) 2 1-Bromo-3-chloropropane BrCH 2 CH 2 CH 2 Cl Diethyl 4-chloro-1,1-
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Unformatted text preview: butanedicarboxylate ClCH 2 CH 2 CH 2 CH(COOCH 2 CH 3 ) 2 1 NaOCH 2 CH 3 1. HO 2 , H 2 O 2. H 1 3. heat Diethyl 2,2-heptanedicarboxylate CH 3 CH 2 CH 2 CH 2 CH 2 C(COOCH 2 CH 3 ) 2 CH 3 2-Methylheptanoic acid CH 3 CH 2 CH 2 CH 2 CH 2 CHCOH O CH 3 Diethyl 2,2-heptanedicarboxylate Diethyl 1,1-hexanedicarboxylate CH 3 CH 2 CH 2 CH 2 CH 2 CH(COOCH 2 CH 3 ) 2 NaOCH 2 CH 3 CH 3 I CH 3 CH 2 CH 2 CH 2 CH 2 C(COOCH 2 CH 3 ) 2 CH 3 ESTER ENOLATES 589...
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This note was uploaded on 09/30/2011 for the course CHM 2210 taught by Professor Reynolds during the Fall '01 term at University of Florida.

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