Chemistry chapter 8-4

Chemistry chapter 8-4 - General Chemistry 110 Prof. B. C....

Info iconThis preview shows pages 1–11. Sign up to view the full content.

View Full Document Right Arrow Icon
General Chemistry 110 Prof. B. C. Sanctuary Otto Maass 224 Bryan.sanctuary@mcgill.ca Office hours: Part 3d Electrons in atoms Chapter 8 Quantum numbers and orbitals 1 Chemistry 110 Chapter 8 Part 3c Quantum II
Background image of page 1

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full DocumentRight Arrow Icon
Chapter 8: Atoms and the Atomic Theory Electromagnetic Radiation Atomic Spectra Quantum Theory The Bohr Atom Two ideas leading to a New Quantum Mechanics Wave Mechanics Quantum Numbers and Electron orbitals Interpretation and Representing: The H atom Electron Spin: a forth quantum number Multi-electron atoms Electronic Configuration Electron Configuration and the Periodic Table 2 Chemistry 110 Chapter 8 Part 3c Quantum II
Background image of page 2
Chapter 8: Atoms and the Atomic Theory Problems: EM radiation: 8-1 to 8-6, 8-8; Atomic spectra: 8-9 to 8-13, 8-17, 8-18; Quantum theory: 8-19 to 8-22, 8-24; Photoelectric effect: 8-25; Bohr Atom8-27 to 8-31; 8-34, 8-36, 8-38; Wave-particle duality: 8-39 to 8-42; Heisenberg Uncertainty: 8-43 to 8-47; Wave mechanics: 8-49 to 8-54; Quantum numbers: 8-55 to 8-60; Shapes of orbits: 8-61 to 8-62, 8-71, 8-72; Electron configs: 8-75 to 8-80, 8-82 to 8-88. 3 Chemistry 110 Chapter 8 Part 3b Quantum
Background image of page 3

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full DocumentRight Arrow Icon
Chapter 8: Atoms and the Atomic Theory Quantum Numbers and Electron orbitals Particle-in-a-box 4 Chemistry 110 Chapter 8 Part 3c Quantum II Free particle, only kinetic energy In the box. Infinite barriers
Background image of page 4
Chapter 8: Atoms and the Atomic Theory Quantum Numbers and Electron orbitals Particle-in-a-box 5 Chemistry 110 Chapter 8 Part 3c Quantum II Infinite barriers 22 2 2 1 2 HE mu p H KE mu mm Ψ= Ψ = = =
Background image of page 5

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full DocumentRight Arrow Icon
Chapter 8: Atoms and the Atomic Theory Quantum Numbers and Electron orbitals Particle-in-a-box 6 Chemistry 110 Chapter 8 Part 3c Quantum II 2 22 2 HE pd H m m dx Ψ= Ψ = = − 2 2 2 2 d E m dx d mE dx Ψ Ψ = −Ψ
Background image of page 6
Chapter 8: Atoms and the Atomic Theory Quantum Numbers and Electron orbitals Particle-in-a-box 7 Chemistry 110 Chapter 8 Part 3c Quantum II 2 22 2 HE pd H m m dx Ψ= Ψ = = − 2 2 2 2 d E m dx d mE dx Ψ Ψ = −Ψ d pi dx = − Momentum operator 2 h π =
Background image of page 7

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full DocumentRight Arrow Icon
8 Chemistry 110 Chapter 8 Part 3c Quantum II Chapter 8: Atoms and the Atomic Theory States : “The Schrödinger Equation” Eigenvalue equations—an example: .. ,, , ls nlm m n HE Ψ= Ψ ( ) ( ) A fx d = Eigenvalue: 2 da = Eigenfunction: ( ) cos sin f x C ax D ax = + 2 2 d A dx = − Determines Solution. ( ) ( ) 2 22 2 A d d mE dx Ψ=− Ψ  2 h π =
Background image of page 8
9 Chemistry 110 Chapter 8 Part 3c Quantum II Chapter 8: Atoms and the Atomic Theory States : “The Schrödinger Equation” Eigenvalue equations—an example: .. ,, , ls nlm m n HE Ψ= Ψ 2 22 2 d mE dx Ψ=− Ψ Eigenvalue: 2 2 2 mE da = = Eigenfunction: ( ) cos sin x C ax D ax + 2 2 d A dx = − Determines Solution. ( ) ( ) 00 L Ψ = Boundary condition:
Background image of page 9

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full DocumentRight Arrow Icon
10 Chemistry 110 Chapter 8 Part 3c Quantum II Chapter 8: Atoms and the Atomic Theory States : “The Schrödinger Equation” Eigenvalue equations—an example: .. ,, , ls nlm m n HE Ψ= Ψ 2 22 2 d mE dx Ψ=− Ψ Eigenvalue: 2 2 2 mE da = = Eigenfunction: ( ) cos sin x C ax D ax + Boundary condition: ( ) ( ) 0 cos0 sin0 0
Background image of page 10
Image of page 11
This is the end of the preview. Sign up to access the rest of the document.

Page1 / 67

Chemistry chapter 8-4 - General Chemistry 110 Prof. B. C....

This preview shows document pages 1 - 11. Sign up to view the full document.

View Full Document Right Arrow Icon
Ask a homework question - tutors are online