Dolbier HW Solutions 521

Dolbier HW Solutions 521 - hexylamine N CH 2 CH CH 2 H N-...

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Secondary amines have the general formula R 2 NH. Those of molecular formula C 4 H 11 N are There is only one tertiary amine (R 3 N) of molecular formula C 4 H 11 N: 22.22 ( a ) The name 2-ethyl-1-butanamine designates a four-carbon chain terminating in an amino group and bearing an ethyl group at C-2. ( b ) The pre f x N - in N -ethyl-1-butanamine identi f es the ethyl group as a substituent on nitrogen in a secondary amine. ( c ) Dibenzylamine is a secondary amine. It bears two benzyl groups on nitrogen. ( d ) Tribenzylamine is a tertiary amine. ( e ) Tetraethylammonium hydroxide contains a quaternary ammonium ion. ( f ) This compound is a secondary amine; it bears an allyl substituent on the nitrogen of cyclo-
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Unformatted text preview: hexylamine. N CH 2 CH CH 2 H N-Allylcyclohexylamine Tetraethylammonium hydroxide (CH 3 CH 2 ) 4 N HO 2 1 Tribenzylamine (C 6 H 5 CH 2 ) 3 N Dibenzylamine C 6 H 5 CH 2 NCH 2 C 6 H 5 H N-Ethyl-1-butanamine CH 3 CH 2 CH 2 CH 2 NCH 2 CH 3 H 2-Ethyl-1-butanamine CH 3 CH 2 CHCH 2 NH 2 CH 2 CH 3 N , N-Dimethylethylamine ( N , N-dimethylethanamine) (CH 3 ) 2 NCH 2 CH 3 Diethylamine ( N-ethylethanamine) (CH 3 CH 2 ) 2 NH N-Methylpropylamine ( N-methyl-1-propanamine) CH 3 NCH 2 CH 2 CH 3 H N-Methylisopropylamine ( N-methyl-2-propanamine) CH 3 NCH(CH 3 ) 2 H AMINES 615...
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