Dolbier HW Solutions 522

Dolbier HW Solutions 522 - compound b This compound is a...

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( g ) Piperidine is a cyclic secondary amine that contains nitrogen in a six-membered ring. N -Allylpiperidine is a tertiary amine. ( h ) The compound is the benzyl ester of 2-aminopropanoic acid. ( i ) The parent compound is cyclohexanone. The substituent (CH 3 ) 2 N group is attached to C-4. ( j ) The suf f x - diamine reveals the presence of two amino groups, one at either end of a three- carbon chain that bears two methyl groups at C-2. 22.23 ( a ) A phenyl group and an amino group are trans to each other on a three-membered ring in this
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Unformatted text preview: compound. ( b ) This compound is a tertiary amine. It bears a benzyl group, a methyl group, and a 2-propynyl group on nitrogen. N-Benzyl-N-methyl-2-propynylamine (pargyline) C 6 H 5 CH 2 CH 2 C CH CH 3 N trans-2-Phenylcyclopropylamine (tranylcypromine) C 6 H 5 H H NH 2 H 2 NCH 2 CCH 2 NH 2 CH 3 CH 3 2,2-Dimethyl-1,3-propanediamine 4-( N , N-Dimethylamino)-cyclohexanone (CH 3 ) 2 N O H CH 3 CHCOCH 2 C 6 H 5 NH 2 O Benzyl 2-aminopropanoate CH 2 N-Allylpiperidine NCH 2 CH 616 AMINES...
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