Dolbier HW Solutions 579

Dolbier HW Solutions 579 - 673 ARYL HALIDES Cl CH3O(b...

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( b ) ( c ) A-2. Draw the structure of the intermediate formed in each reaction of problem A-1. A-3. Suggest synthetic schemes by which chlorobenzene may be converted into ( a ) 2,4-Dinitroanisole (1-methoxy-2,4-dinitrobenzene) ( b ) p -Isopropylaniline A-4. Write a mechanism using resonance structures to show how a nitro group directs ortho, para in nucleophilic aromatic substitution. A-5. What is the cycloaddition product of the following reaction? What is the structure of the short-lived intermediate formed in this reaction? PART B B-1. The reaction most likely occurs by which of the following mechanisms?
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This note was uploaded on 10/03/2011 for the course CHM 2210 taught by Professor Reynolds during the Fall '01 term at University of Florida.

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