Dolbier HW Solutions 587

Dolbier HW Solutions 587 - dimethyl. ( e ) The compound is...

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24.12 ( a ) The compound is named as a derivative of phenol. The substituents (ethyl and nitro) are cited in alphabetical order with numbers assigned in the direction that gives the lowest number at the f rst point of difference. ( b ) An isomer of the compound in part ( a ) is 4-ethyl-3-nitrophenol. ( c ) The parent compound is phenol. It bears, in alphabetical order, a benzyl group at C-4 and a chlorine at C-2. ( d ) This compound is named as a derivative of anisole, C 6 H 5 OCH 3 . Because multiplicative pre- f xes (di, tri-, etc.) are not considered when alphabetizing substituents, isopropyl precedes
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Unformatted text preview: dimethyl. ( e ) The compound is an aryl ester of trichloroacetic acid. The aryl group is 2,5-dichlorophenyl. 2,5-Dichlorophenyl trichloroacetate Cl Cl 1 2 3 4 5 6 OCCCl 3 O 4-Isopropyl-2,6-dimethylanisole OCH 3 CH 3 H 3 C CH(CH 3 ) 2 1 2 3 4 5 6 Cl CH 2 HO 1 2 3 4 5 6 4-Benzyl-2-chlorophenol OH NO 2 CH 2 CH 3 1 2 3 4 5 6 4-Ethyl-3-nitrophenol 3-Ethyl-4-nitrophenol OH CH 2 CH 3 NO 2 1 2 3 4 5 6 PHENOLS 681...
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This note was uploaded on 10/03/2011 for the course CHM 2210 taught by Professor Reynolds during the Fall '01 term at University of Florida.

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