Dolbier HW Solutions 632

Dolbier HW - This is in fact not a different sugar but simply 1-mannose rotated through an angle of 180 ° CH 2 OH CHO HO H H H HO H OH OH CHO CH 2

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Oxidation gives the aldaric acid This is the same aldaric acid as that provided by one of the structures given as either ( 1 )-glucose or ( 1 )-mannose. That Fischer projection therefore corresponds to ( 1 )-glucose. The structure of ( 1 )-mannose is therefore A sugar that yields the same aldaric acid is
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Unformatted text preview: This is, in fact, not a different sugar but simply ( 1 )-mannose rotated through an angle of 180 ° . CH 2 OH CHO HO H H H HO H OH OH CHO CH 2 OH HO H H H HO H OH OH CHO CH 2 OH H H H H HO OH OH OH This must be ( 1 )-glucose. CO 2 H CO 2 H H H H H HO OH OH OH 726 CARBOHYDRATES...
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This note was uploaded on 10/03/2011 for the course CHM 2210 taught by Professor Reynolds during the Fall '01 term at University of Florida.

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