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Dolbier HW Solutions 643

Dolbier HW Solutions 643 - 737 LIPIDS(d The methyl groups...

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( d ) The methyl groups that are lost are the methyl substituents at C-2 and C-10 plus the methyl group that is C-1 of squalene 2,3-epoxide. 26.13 Tracking the 14 C label of 14 CH 3 CO 2 H through the complete biosynthesis of cholesterol requires a systematic approach. First, by analogy with Problem 26.11, we can determine the distribution of 14 C (denoted by *) in squalene 2,3-epoxide. Next, follow the path of the
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