Dolbier HW Solutions 689

Dolbier HW Solutions 689 - H 3 PO 4 2 H 1 OH 1 H OH 2 H 1 H...

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APPENDIX A 783 A-8. A-9. Step 1: Protonation Step 2: Dissociation Step 3: Deprotonation A-10. A-11. A-12. Cis isomer: Trans isomer: The trans isomer will react faster because its most stable conformation (with the isopropyl group equatorial) has an axial Cl able to undergo E2 elimination. A-13. Rearrangement (hydride migration) occurs to form a more stable carbocation.
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Unformatted text preview: H 3 PO 4 2 H 1 OH 1 H OH 2 H 1 H 2 O 1 Cl (CH 3 ) 2 CH CH(CH 3 ) 2 Cl Cl (CH 3 ) 2 CH (CH 3 ) 2 CH Cl 1 H Br CH 3 CH 3 Br 2 CH 3 O 2 NaOCH 2 CH 3 CH 3 CH 2 OH Br (major) 1 1 H H OH 2 1 H 3 O 1 OH 2 1 1 1 H 2 O 1 OH H OH 2 1 OH 2 1 CH 2 Br CH 3 CH 2 C CH 3 CH 3...
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This note was uploaded on 10/03/2011 for the course CHM 2210 taught by Professor Reynolds during the Fall '01 term at University of Florida.

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