Dolbier HW Solutions 692

Dolbier HW Solutions 692 - S )-5-Chloro-2-hexene A-3. ( a )...

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A-10. A-11. B-1. ( c ) B-2. ( a ) B-3. ( c ) B-4. ( d ) B-5. ( d ) B-6. ( e ) B-7. ( b ) B-8. ( b ) B-9. ( b ) B-10. ( b ) B-11. ( a ) B-12. ( e ) B-13. ( e ) CHAPTER 7 A-1. ( a ) 1 and 2, both achiral; identical ( b ) 3 and 4, both chiral; enantiomers ( c ) 5 chiral, 6 achiral (meso); diastereomers ( d ) 7 and 8, both chiral; diastereomers ( e ) 9 and 10, both chiral; diastereomers A-2. 3: ( R )-2-Chlorobutane; 4: ( S )-2-Chlorobutane 5: 6: 7: (2 S ,3 R) -2,3-Dibromopentane; 8: (2 R ,3 R )-2,3-Dibromopentane 9: (2 E ,5 R )-5-Chloro-2-hexene; 10: (2 Z ,5
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Unformatted text preview: S )-5-Chloro-2-hexene A-3. ( a ) Three; meso form is possible. ( c ) Four; no meso form possible. ( b ) Eight; no meso form possible. HO HO R S OH OH R R C (CH 3 ) 2 C O (2 mol) 1. O 3 2. H 2 O, Zn (CH 3 ) 2 CHCCH 3 CH 3 Br B (CH 3 ) 2 C C(CH 3 ) 2 C (CH 3 ) 2 CHC CH 2 CH 3 A NaOCH 2 CH 3 CH 3 CH 2 OH HBr 1 HCl hydride shift 1 1 Cl Cl Cl 2 Cl 2 786 APPENDIX A...
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This note was uploaded on 10/03/2011 for the course CHM 2210 taught by Professor Reynolds during the Fall '01 term at University of Florida.

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