Dolbier HW Solutions 694

Dolbier HW Solutions 694 - 788 APPENDIX A A-9. Two: (2R,3S

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A-9. Two: (2 R ,3 S )-2-bromo-3-chlorobutane and (2 S ,3 S )-2-bromo-3-chlorobutane; they are di- astereomers. A-10. B-1. ( c ) B-2. ( c ) B-3. ( b ) B-4. ( d ) B-5. ( b ) B-6. ( c ) B-7. ( d ) B-8. ( d ) B-9. ( b ) B-10. ( c ) B-11. ( d ) B-12. ( d ) B-13. ( e ) B-14. ( b ) CHAPTER 8 A-1. ( a )C H 3 CH 2 CH 2 CH 2 OCH 2 CH 3 ( e ) ( b )( f ) ( c ) ( g ) ( d ) A-2. (CH 3 ) 2 CHO 2 Na 1 1 CH 3 CH 2 CH 2 Br A-3. ( a ) ( b ) A-4. Step 1: Ionization to form a secondary carbocation H 3 C CH 3 CH 3 C CHCH 3 Cl CH 3 CH 3 CH 3 C CHCH 3 1 Cl 2 H 2 O 1 C H OH CH 3 CH 2 CH 2 H 3 C C H OTs CH 3 CH 2 CH 2 H 3 C pyridine
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