W03 problems6a key

W03 problems6a key - Problem Set VI(Answers Aldehydes and Ketones Winter 2003 1 Draw the structure for each of the compounds given below a

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H O O OO O O O H O Cl O O O NH 2 HS SH PPh 3 EtOH H + H + H + EtO OEt S S OH H HO CH 3 OH H N O Problem Set VI (Answers) 1. Draw the structure for each of the compounds given below. a) trans -2,6-Diacetylcyclohexanone 2. Draw all possible products for the transformations below. a) Winter 2003 Aldehydes and Ketones b) c) d) e) f) g) h) b) trans -2,5-Diethyltetrahydrofuran 1. CH 3 MgBr 2. H 3 O + 1. CH 3 Li 2. H 3 O + Mg o 1. H 2 NNH 2 2. KOH / heat Raney Ni +
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O O OH NH 2 O HO H O H O H O PPh 3 3. H 3 O + 2. H 2 CrO 4 H 2 CrO 4 H O OH 1. DHP, H + H + H + H + H O Cl H O OH OH O 3 O HO H HO O O OO HO O O H N O H O OH HO H O O Problem Set VI (Answers) 3. Provide the reagent(s) required (they all require more than one step) to perform the following transformations. i) Winter 2003 Aldehydes and Ketones (Page 2) 1. LiAlH 4 2. H 3 O + j) k) l) m)
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This note was uploaded on 04/05/2008 for the course CHEM 30B taught by Professor Rubin during the Winter '05 term at UCLA.

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W03 problems6a key - Problem Set VI(Answers Aldehydes and Ketones Winter 2003 1 Draw the structure for each of the compounds given below a

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