W03 problems1b

W03 problems1b - regioisomers and/or stereoisomers whenever...

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Problem Set 1 (Chepter 9 Alcohols and Thiols) TA: Danny Ng 1/13/2002 A . S y n t h e s i s o f A l c o h o l s f r o m A l k e n e s ( R e v i e w ) 1. Provide the missing reagents or products for the following reactions. Include all possible stereoisomers whenever applicable 1. Hg(OAc) 2 , H 2 O 2. NaBH 4 OH B . N o m e n c l a t u r e s o f A l c o h o l 2. (i) Provide the structure for the following compounds and (ii) Identify whether the alcohols are primary, secondary, or tertiary. (a) 5-bromo-1,2,6-trimethylcycloheptanol (b) cis -1,2,4-cyclooctanetriol H 2 SO 4 H 2 O
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Problem Set 1 (Chepter 9 Alcohols and Thiols) TA: Danny Ng 1/13/2002 C . R e a c t i o n s o f A l c o h o l s 3. Provide the missing reagents or products for the following reactions. Include all possible
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Unformatted text preview: regioisomers and/or stereoisomers whenever applicable (Indicate the major isomers). 1. NaNH 2 2. 1-bromopropane OH H H HO HCl SOCl 2 , pyridine OH 1. H 3 C S O O Cl pyridine 2. NaI OH HO O O O O H OH OH OH excess PBr 3 F OH OH PCC OH OH OH HIO 4 OH HBr OH HO HBr H 2 SO 4 O Problem Set 1 (Chepter 9 Alcohols and Thiols) TA: Danny Ng 1/13/2002 H 2 SO 4 , heat 4. Predict the major products for the following reactions and explain the difference in reactivity. H 2 SO 4 , heat 5. Explain the following reaction with a mechanism. O...
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W03 problems1b - regioisomers and/or stereoisomers whenever...

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