8487-Exam-2B-answers-KEY

8487-Exam-2B-answers-KEY - Wednesday, March 16, 2011 CHM...

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Wednesday, March 16, 2011 CHM 2211-8487 Exam #2 Form B Answer Page 1 of 2 Answer sheet pts. Please LAST PRINT NAME: First name: UFID: /100 Put your answers in the spaces, or check R your answer 1. ( 5 pts ) Name the compound: Write (a) the systematic name (b) the common name. O O methyl butyrate methyl butanoate (a) Systematic name (b) Common name _____ 2. ( 16 pts ) (a) – (f) Mechanism for the hydrolysis of an acid chloride . Steps 1 4 . Ph Cl O H 2 O Ph O Cl OH 2 (b) TCAI-1 1 Ph (e) Resulting species 2 OH O + (a) Curved electron arrows Ph O Cl OH (c) TCAI-2 3 H (d) Curved el arrows Ph (f) Final products OH O + H–Cl 4 H Cl Classify reaction steps 1 , 2 , 3 (check the relevant type of reaction ) [No partial credit]: (g) Step 1 is an £ A/B, £ elimination, R Nu:/El reaction. (h) Step 2 is an R A/B, £ elimination, £ Nu:/El reaction. (i) Step 3 is an £ A/B, R elimination, £ Nu:/El reaction. _____ 3. ( 7 pts ) Products formed upon reaction of succinic anhydride with excess of (a) NaOH/H 2 O, (b) NH 3 . O
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8487-Exam-2B-answers-KEY - Wednesday, March 16, 2011 CHM...

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