Friday, April 1, 2011 CHM 2211-8487 Quiz #09 Form BPage 1 of 1Please Last PRINTname:First name: UFID:______/20 pts. Put your answers in the spaces, or check Ror insert your answer 1.(6pts) For the electrophilic aromatic substitution (EAS) reaction of N-phenylacetamidewith HNO3/H2SO4: (a)Draw (complete) the most important contributing structureof the p-substitutedcation intermediate. (b)Draw (complete) the structure of the resulting p-disubstituted benzene product. HNCHNO3, H2SO4HNCOCH3HNO2HSO4(a) The most important contributing structureof the p-substituted cation intermediate.HNCOCH3H2SO4(b) p-Disubstituted benzeneproduct.NO2+OCH3– H2O_____2.(3 pts) Arrange components A– Din order of decreasing reactivitytoward EAS. NH3CCH3CH3CH=OOHClBCAD>>>Most reactive>Least reactiveBDCA_____3.(8 pts) (a)Draw (complete) the product structureresulting from the EAS reaction of
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