PS5 - Page 1 of 4 Fall 2011 5.112 PRINCIPLES OF CHEMICAL...

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Page 1 of 4 Fall 2011: 5.112 PRINCIPLES OF CHEMICAL SCIENCE Problem Set #5 Due: Friday, October 21, 2011 by 11 am in 4-273 Reading Assignment for Material Covered in Lectures #16-18: 5th edition book 4th edition book Major technique 1 – Infrared spectroscopy – pg. 90-1 Major technique 1 – Infrared spectroscopy – pg. 92-3 Chapter 2 Chapter 2 Box 2.2 - pg. 83 - How Do We Know the Length of a Chemical Bond? Box 2.2 - pg. 84 - How Do We Know the Length of a Chemical Bond? Chapter 7 Chapter 6 Section 7.7 – A Molecular Interlude –The Origin of Internal Energy Section 6.7 – A Molecular Interlude –The Origin of Internal Energy Section 676 - State Functions –p 247 -248 Section 6.6 - State Functions –p 226 -227 Section 7.13 - Reaction Enthalpies Section 6.13 - Reaction Enthalpies Section 7.15 - Standard Reaction Enthalpies Section 6.15 - Standard Reaction Enthalpies Section 6.16 - Combining Reaction Enthalpies: Hess’s Law Section 6.16 - Combining Reaction Enthalpies: Hess’s Law Section 7.17 - The Heat Output of Reactions Section 6.17 - The Heat Output of Reactions Section 7.18 - Standard Enthalpies of Formation Section 6.18 - Standard Enthalpies of Formation Section 7.20 - Bond Enthalpies Section 6.20 - Bond Enthalpies Chapter 8 Chapter 7 Section 8.1 - Spontaneous Change Section 7.1 - Spontaneous Change Section 8.2 - Entropy and Disorder Section 7.2 - Entropy and Disorder Section 8.7 - Standard Reaction Entropies Section 7.7 - Standard Reaction Entropies Section 8.11 - Equilibrium Section 7.11 - Equilibrium Section 8.12 - Focusing on the System Section 7.12 - Focusing on the System Section 8.13 – Gibbs Free Energy of Reaction Section 7.13 – Gibbs Free Energy of Reaction Section 8.15 - The Effect of Temperature Section 7.15 - The Effect of Temperature Section 8.16-Impact on Biology: Gibbs Free Energy Changes in Biological Systems Section 7.16-Impact on Biology: Gibbs Free Energy Changes in Biological Systems Chapter 10 Chapter 9 Section 10.1 – Reversibility of Reactions Section 9.1 – Reversibility of Reactions Section 10.2 – Equilibrium and Law of Mass Action Section 9.2 – Equilibrium and Law of Mass Action Section 10.3 – Thermodynamic Origin of Equilibrium Constants Section 9.3 – Thermodynamic Origin of Equilibrium Constants Section 10.4 – Extent of Reaction Section 9.4 – Extent of Reaction Section 10.5 – Direction of Reaction Section 9.5 – Direction of Reaction Section 10.8 – Using Equilibrium Constants Section 9.8 – Using Equilibrium Constants
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PS5 - Page 1 of 4 Fall 2011 5.112 PRINCIPLES OF CHEMICAL...

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