es key - 2) H 3 O + workup heat (-CO 2 ) 3) H 3 O + workup...

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Questions from Organic Chemistry 5 th ed. by Paul R. Young, pages 155 and 156 CHEM 233 Acetoacetic Esters and Malonic Esters in Synthesis Answers OMe O MeO O 1) 1 equiv. MeONa, MeOH 2) 1 equiv. PhCHBrCH 3 OMe O MeO O 3) H 3 O + workup H 3 C Ph 1) NaOH (aq) 2) H 3 O + workup OH O HO O H 3 C Ph heat (-CO 2 ) OH O H 3 C Ph racemate OMe O MeO O 1) 1 equiv. MeONa, MeOH 2) 1 equiv. OMe O MeO O 3) H 3 O + workup 1) NaOH (aq) 2) H 3 O + workup heat (-CO 2 ) Br OH O OH O HO O
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Questions from Organic Chemistry 5 th ed. by Paul R. Young, pages 155 and 156 OMe O MeO O 1) excess MeONa, MeOH OMe O MeO O 1) NaOH (aq) 2) H 3 O + workup heat (-CO 2 ) 3) H 3 O + workup Br Br 2) OH O HO O OH O CO 2 H mixture of diastereomers * OMe O H 3 C O 1) 1 equiv. MeONa in MeOH 2) 1 equiv. PhCH 2 Cl OMe O H 3 C O 1) NaOH (aq) 2) H 3 O + workup heat (-CO 2 ) Ph OH O 3) H 3 O + workup OH O H 3 C O Ph OMe O H 3 C O 1) 1 equiv. MeONa in MeOH 2) 1 equiv. OMe O H 3 C O 1) NaOH (aq)
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Unformatted text preview: 2) H 3 O + workup heat (-CO 2 ) 3) H 3 O + workup Cl OH O H 3 C O H 3 C O Questions from Organic Chemistry 5 th ed. by Paul R. Young, pages 155 and 156 OMe O H 3 C O 1) 1 equiv. MeONa in MeOH 2) 1 equiv. OMe O H 3 C O 1) NaOH (aq) 2) H 3 O + workup heat (-CO 2 ) 3) H 3 O + workup Br OH O H 3 C O H 3 C O OMe O H 3 C O 1) excess MeONa in MeOH 2) excess OMe O H 3 C O 1) NaOH (aq) 2) H 3 O + workup heat (-CO 2 ) 3) H 3 O + workup I H 3 C O OH O H 3 C O OMe O H 3 C O 1) excess MeONa in MeOH 2) 1 equiv. OMe O H 3 C O 1) NaOH (aq) 2) H 3 O + workup heat (-CO 2 ) 3) H 3 O + workup Br Br OH O H 3 C O H 3 C O...
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es key - 2) H 3 O + workup heat (-CO 2 ) 3) H 3 O + workup...

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