Lecture 5 - 1,3-Butadiene (16.1) Planar due to significant...

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1 Reading for Friday ± Chapter 16: 16.8-16.12 ± We will not be covering 16.15 Mon. 6:00-7:30 pm MAL 3092 Tues. 2:30-4:00 PM MAL 2007 Wed. 5:00-6:30 PM MAL 2001 Thurs. 9:30-10:50 AM MAL 1003 Sat. 11:00 AM-1:00 PM MAL 2007 CHEM 626 PLUS Sessions First ARIS Quiz ± Available Wednesday Feb. 2 ± Due at 11:59 pm on the evening of Sunday, Feb. 6 Chapter 16 Conjugation, Resonance and Dienes Conjugation (16.1) When p orbitals overlap on three or more adjacent atoms 1,3-Butadiene is the simplest neutral conjugated molecule
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Unformatted text preview: 1,3-Butadiene (16.1) Planar due to significant double bond character between C2 and C3 This is due to -electron delocalization 2 Conjugated vs. Isolated Dienes (16.1) Allylic Carbocations (16.1; 16.2) Stabilized by resonance Electron Delocalization, Hybridization and Geometry (16.5) In any system X=Y-Z: , Z is sp 2 hybridized and the nonbonded electron pair occupies a p orbital to make the system conjugated...
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This note was uploaded on 10/24/2011 for the course CHEMISTRY 623 taught by Professor Benson during the Spring '11 term at Kansas.

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Lecture 5 - 1,3-Butadiene (16.1) Planar due to significant...

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