Lecture 21 - Reading for Monday PLUS Sessions NEXT WEEK Mon...

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1 Reading for Monday ± Finish Chapter 20 Mon. 6:00-7:30 pm MAL 3092 Tues. 2:30-4:00 PM MAL 2007 Wed. 5:00-6:30 PM MAL 2001 Thurs. 9:30-10:50 AM MAL 1003 Sat. 11:30 AM-1:00 PM MAL 2007 PLUS Sessions NEXT WEEK Chapter 20 Introduction to Carbonyl Chemistry Organometallic Reagents (20.9) Contain a carbon-metal bond Types we will examine: Organolithium reagents (RLi) Organomagnesium reagents (RMgX) Grignard reagents Organocuprates (R 2 CuLi) Gilman reagents Acetylide anions (RC C: ) Organometallic Reagents (20.9) Role of diethyl ether in Grignard Reagent formation Complex formation Stabilizes and solubilizes reagent Organometallic Reagents (20.9) Strong nucleophiles React with electrophilic carbon atoms to form new C-C bonds
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2 Organometallic Reagents: Reaction with Aldehydes and Ketones (20.10) Grignard Reagents and Organolithium reagents (including lithium acetylides) react with ketones and aldehydes to produce alcohols Organocuprates do not react Water and other protic solvents must
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Lecture 21 - Reading for Monday PLUS Sessions NEXT WEEK Mon...

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