Lecture 30 - • To 1º amines (using LiAlH 4 ) • To...

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1 Reading for Friday Chapter 23: 23.6-23.9 ARIS Quiz #6 Available NOW Due Sunday April 10 at 11:59 pm 3 rd Exam Next Thursday! April 14 th 6-7:30 PM 120 Budig Exam 3 will cover Chapters 20, 21 and 22 (all sections except those skipped) Exam 3 Review Session Tuesday April 12 th 6:00 PM 1001 Malott Mon. 6:00-7:30 pm MAL 3092 Tues. 2:30-4:00 PM MAL 2007 PLUS Sessions NEXT WEEK Chapter 22 Carboxylic Acids and Their Derivatives: Nucleophilic Acyl Substitution Rxns. of Nitriles (22.18) Hydrolysis to carboxylic acids Acid-catalyzed Base-promoted Reduction
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Unformatted text preview: • To 1º amines (using LiAlH 4 ) • To aldehydes (using DIBAL-H) • Rxn. with RMgX or RLi to give ketones 2 Testing mechanisms using isotopes (Special Topic) Reaction mechanisms can NEVER be proven Chemists instead try to eliminate all alternate possibilities Isotopic labeling is a common way of doing this Tert-Butyl Esters (Special Topic) Can be hydrolyzed under conditions that other esters are stable, because a different mechanism is involved Useful as a chemoselective protecting group...
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This note was uploaded on 10/24/2011 for the course CHEMISTRY 623 taught by Professor Benson during the Spring '11 term at Kansas.

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Lecture 30 - • To 1º amines (using LiAlH 4 ) • To...

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