valemid - Loeng 8 U = q w w = Pex V w = nRT ln V final...

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Loeng 8 R C m V 2 3 , = (üheaatomilised molekulid) R C m V 2 5 , = (lineaarsed molekulid) R C m V 3 , = (mittelineaarsed molekulid) H r º = Σ n H f º(saadused) – Σ n H f º(lähteained) H B (X-Y) = [ H m º(X, g) + H m º(Y, g)] – H m º(X-Y, g) H r,2 º = H r,1 º + C P ( T 2 T 1 ) C P = Σ nC P,m (produktid) – Σ nC P,m (lähteained) Loeng 9 w q U + = V P w ex - = initial final V V nRT w ln - = PV U H + = T q C = T U C V = T H C P = R C C m V m P + = , , nRT U V P U H + = + = T q S rev = 1 2 ln T T C S = 2 1 1 2 ln ln P P nR V V nR S = = keem aur aur T H S =
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G r º = Σ n G f º(saadused) – Σ n G f º(lähteained) Loeng 10 f = k p + 2 T H S süst keskk - = TS H G - = sum S T G S T H G - = - = ja G w e = max , ( 29 ( 29 P RT g G P g G m m ln , + = o R S RT H RT G P aur aur aur o o o + - = - = ln - = 2 1 1 2 1 1 ln T T R H P P aur o gaas H P k s = lahusti aine lah m lahusti aine lah aine lah m n c n n n x . . . = + = puhas lahusti lahusti P x P = m ikc T = iRTc = Π puhas B segu B puhas A segu A B A sum P x P x P P P , , , , + = + =
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Loeng 11 Loeng 12 J m m a RT J G J G ln ) ( ) ( + = o Q RT G G r r ln + = o b B a A d D c C a a a a Q = [ ] [ ] [ ] [ ] b B a A d D c C b a d c b B a A d D c C p p p p või B A D C a a a a K = ( 29 c n c n p K RT K p RTc K =
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