3580 Spring 2011_PSET 5

3580 Spring 2011_PSET 5 - count and total electron count...

Info iconThis preview shows page 1. Sign up to view the full content.

View Full Document Right Arrow Icon
Chemistry 3580 Spring 2011 Prof. William Dichtel Homework: Problem Set #5 Will not be collected; key will be posted on 3/3/11 Textbook Problems: Ch 18 (p 877): 18.44(a-d; g-k), 18.49, 18.61, 18.62, 18.64(a-l), 18.65 (a-i), 18.66, 18.76, 18.77 (1) Give the correct oxidation state, d n count, and electron count of the following transition metal-containing compounds: (2) Propose a mechanism for the following transformation. Name each process that occurs around the metal center (e.g., ligand insertion) and calculate the oxidation state, d n electron
Background image of page 1
This is the end of the preview. Sign up to access the rest of the document.

Unformatted text preview: count, and total electron count for each intermediate that contains the transition metal. (3) Provide the reagents and any other organic compounds needed to synthesize the indicated product from the starting material shown. No synthesis will require more than f ve steps. However, some or all may require fewer than f ve steps. (a) Ni Ph 3 P Ph 3 P Cl (b) TiCl 2 (c) Pd OH P P Bu Bu Bu Bu Bu Bu Ru PCy 3 Ph Cl Cl (d) Cl O Br Cl O Pd(PPh 3 ) 4 NEt 3 Cl O Br Cl O Br Ru PCy 3 PCy 3 Ph Cl Cl Cy = cyclohexyl NO 2 NH 2 NO 2...
View Full Document

This note was uploaded on 11/01/2011 for the course CHEM 3580 taught by Professor Sogah, d during the Spring '08 term at Cornell.

Ask a homework question - tutors are online