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Unformatted text preview: 4.3. EXPECTATION VALUE AND STANDARD DEVIATION 49 What are the expectation values of energy, square angular momentum, and zangular momen tum for this state? Answer: Note that the square coefficients of the eigenfunctions 211 and 21 1 are each 1 2 , so each has a probability 1 2 in the 2p x state. Eigenfunction 211 has an energy eigenvalue E 2 , and so does 21 1 , so the expectation value of energy in the 2p x state is ( E ) = 1 2 E 2 + 1 2 E 2 = E 2 = 4 . 3 eV. This is as expected since the only value that can be measured in this state is E 2 . Similarly, eigenfunction 211 has a square angular momentum eigenvalue 2 h 2 , and so does 21 1 , so the expectation value of square angular momentum in the 2p x state is that value, ( L 2 ) = 1 2 2 h 2 + 1 2 2 h 2 = 2 h 2 . Eigenfunction 211 has a zangular momentum eigenvalue h , and 21 1 has h , so the expec tation value of zangular momentum in the 2p x state is ( L z ) = 1 2 h 1 2 h = 0 Measurements in which the zangular momentum is found to be h average out against those...
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 Fall '11
 GARVIN
 Angular Momentum, Energy, Momentum

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