Chairflip - interactions R Ratio A:E H 1:1 CH 3 18:1 CH 2 CH 3 21:1 CH(CH 3 2 35:1 C(CH 3 3 4800:1 F 1.5:1 Cl 2.4:1 Br 2.2:1 I 2.2:1 OH 4.5:1 A E R

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pull this carbon down pull this carbon up A B C D E 12.1 6.8 relative energy (kcal/mol) A B C D E
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The larger the group on the cyclohexane ring, the more it wants to be situated in an equatorial position to minimize 1,3-diaxial
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Unformatted text preview: interactions. R Ratio A:E H 1:1 CH 3 18:1 CH 2 CH 3 21:1 CH(CH 3 ) 2 35:1 C(CH 3 ) 3 4800:1 F 1.5:1 Cl 2.4:1 Br 2.2:1 I 2.2:1 OH 4.5:1 A E R R H H euquatorial R group axial R group...
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This note was uploaded on 11/13/2011 for the course CHEM 281 taught by Professor Williams during the Spring '11 term at Simon Fraser.

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Chairflip - interactions R Ratio A:E H 1:1 CH 3 18:1 CH 2 CH 3 21:1 CH(CH 3 2 35:1 C(CH 3 3 4800:1 F 1.5:1 Cl 2.4:1 Br 2.2:1 I 2.2:1 OH 4.5:1 A E R

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