Formula sheet Exam _3

Formula sheet Exam _3 - =G/N = G m dp/dT = trs S / trs V...

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Formula Sheet (Exam #3) Chapters 1 and 2 p=F(T, V, n) V m = V/ n p = F / A pV= nRT C= (3RT/M) 1/2 p j = x j p p= p A + p B + … pV m = RTZ pV m = RT(1 + B’p + C’p 2 …) PV m = RT(1 + B/V + C/V 2 …) (p+a/V m 2 )(V m -b)= RT Z c = p c V c /RT c p r = p/p C dw = -Fdz dw = -p ext dV C V = C p = H = U + pV C p – C v = nR PV y = constant r H 0 = - = - Π T = α = κ = - μ = μ Τ = R=8.314 J/mol K R=8.206 x10 -2 dm 3 atm K -1 mol -1 1 atm = 101,325 Pa Chapter 3 and 4 dS=dq rev /T S sur = q sur /T S = k ln W η = |w|/|q h | η = 1-T c /T h dS ≥ dq/T trs S = trs H/T trs r S 0 = - A= U – TS G = H – TS r G 0 = - dU = TdS – p dV Maxwell relations cross multiply to give TS and PV
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derivative of left side gives fixed quantity on right side sign please! F= C – P + 2
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Unformatted text preview: =G/N = G m dp/dT = trs S / trs V d(ln p)/dT = vap H/RT 2 Chapter 5 G m = G m + RT ln (f/p ) f = p V J = p, T, n J = G J = p, T, n G = n A A + n B B = 0 = + RT ln (p/p ) mix G = n A RT ln(p A /p) + n B RT ln (p A /p) mix G = nRT {x A ln x A + x B ln x B } mix S = -nR {x A ln x A + x B ln x B } = + RT ln (p ) p = x p * p = K p * a A = p A /p A * a A = A x A A = x A p A */ [p B * + (p A *-p B *)x A ] p=p A* p B*/ [p B * + (p A *-p B *)y A ]...
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Formula sheet Exam _3 - =G/N = G m dp/dT = trs S / trs V...

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