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Formula sheet Exam _3

# Formula sheet Exam _3 - μ =G/N = G m dp/dT = ∆ trs S ∆...

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Formula Sheet (Exam #3) Chapters 1 and 2 p=F(T, V, n) V m = V/ n p = F / A pV= nRT C= (3RT/M) 1/2 p j = x j p p= p A + p B + … pV m = RTZ pV m = RT(1 + B’p + C’p 2 …) PV m = RT(1 + B/V + C/V 2 …) (p+a/V m 2 )(V m -b)= RT Z c = p c V c /RT c p r = p/p C dw = -Fdz dw = -p ext dV C V = C p = H = U + pV C p – C v = nR PV y = constant r H 0 = - = - Π T = α = κ = - μ = μ Τ = R=8.314 J/mol K R=8.206 x10 -2 dm 3 atm K -1 mol -1 1 atm = 101,325 Pa Chapter 3 and 4 dS=dq rev /T S sur = q sur /T S = k ln W η = |w|/|q h | η = 1-T c /T h dS ≥ dq/T trs S = trs H/T trs r S 0 = - A= U – TS G = H – TS r G 0 = - dU = TdS – p dV Maxwell relations cross multiply to give TS and PV

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derivative of left side gives fixed quantity on right side sign please! F= C – P + 2
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Unformatted text preview: μ =G/N = G m dp/dT = ∆ trs S / ∆ trs V d(ln p)/dT = ∆ vap H/RT 2 Chapter 5 G m = G m + RT ln (f/p ) f = φ p V J = p, T, n’ μ J = G J = p, T, n’ G = n A μ A + n B μ B = 0 μ = μ + RT ln (p/p ) ∆ mix G = n A RT ln(p A /p) + n B RT ln (p A /p) ∆ mix G = nRT {x A ln x A + x B ln x B } ∆ mix S = -nR {x A ln x A + x B ln x B } μ Α = μ Α + RT ln (p Α ) p Α = x Α p Α * p Α = K Α p Α * a A = p A /p A * a A = γ A x A γ A = x A p A */ [p B * + (p A *-p B *)x A ] p=p A* p B*/ [p B * + (p A *-p B *)y A ]...
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Formula sheet Exam _3 - μ =G/N = G m dp/dT = ∆ trs S ∆...

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